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Home/JEE MAINS/chemistry/amines
Curated PYQ Collection

Top 50 Most Repeated AMINES PYQs | JEE MAINS

A curated collection of the most important questions from AMINES, fully solved with step-by-step concepts to prepare for JEE MAINS.

Question #1

Practice Question

A.Butan-1‑ol
B.Butan‑1‑amine
C.Butan‑2‑amine
D.Butan‑1‑yl bromide (unchanged)

Concept Applied

In Gabriel synthesis, the alkyl halide first reacts with potassium phthalimide to give N‑alkylphthalimide. Subsequent hydrolysis liberates the primary...

Read Full Step-by-Step Solution →

Question #2

Practice Question

A.A. A reaction that produces amines
B.B. A reaction that produces diazonium salts
C.C. A reaction that produces phenols
D.D. A reaction that produces aniline

Concept Applied

The Sandmeyer reaction is a type of electrophilic aromatic substitution reaction that produces phenols from diazonium salts....

Read Full Step-by-Step Solution →

Question #3

Practice Question

A.Aniline
B.N,N-Dimethylaniline
C.Methylaniline
D.Styrene

Concept Applied

Exhaustive methylation of aniline gives quaternary ammonium salt; Hoffmann elimination yields least substituted alkene — styrene....

Read Full Step-by-Step Solution →

Question #4

Practice Question

A.NaNO₂, HCl, 0–5 °C
B.NaNO₂, NaOH, 25 °C
C.KNO₃, H₂SO₄, 50 °C
D.NaNO₂, H₂SO₄, 0–5 °C

Concept Applied

Diazotisation requires nitrous acid (generated from NaNO₂ + HCl) at low temperature (0–5 °C) to keep the unstable diazonium ion from decomposing....

Read Full Step-by-Step Solution →

Question #5

Practice Question

A.Aniline > p-toluidine > ammonia
B.Ammonia > aniline > p-toluidine
C.p-Toluidine > aniline > ammonia
D.Ammonia > p-toluidine > aniline

Concept Applied

Electron-donating groups increase basicity; aniline is weakest due to resonance....

Read Full Step-by-Step Solution →

Question #6

Practice Question

A.Ethylamine
B.Methylamine
C.Propylamine
D.Dimethylamine

Concept Applied

In Hofmann bromamide reaction, R-CONH₂ → R-NH₂ with loss of CO₂. The alkyl group migrates, so carbon count decreases by one. Propanamide (C₂H₅CONH₂) g...

Read Full Step-by-Step Solution →

Question #7

Practice Question

Concept Applied

Diazotisation follows a 1:1 stoichiometry between aniline and NaNO₂. Hence, 0.10 mol of NaNO₂ is needed....

Read Full Step-by-Step Solution →

Question #8

Practice Question

A.Primary amine with one carbon less than the original amide
B.Alkyl bromide
C.Nitrile
D.Carboxylic acid

Concept Applied

The Hofmann bromamide reaction proceeds via bromination of the amide followed by base‑induced elimination, resulting in decarboxylation and formation ...

Read Full Step-by-Step Solution →

Question #9

Practice Question

A.Primary aliphatic amine
B.Secondary amine
C.Tertiary amine
D.Aromatic amine

Concept Applied

Gabriel synthesis produces only primary aliphatic amines via alkylation of phthalimide....

Read Full Step-by-Step Solution →

Question #10

Practice Question

A.+I effect of NH₂
B.Hyperconjugation
C.+M effect of NH₂
D.-I effect of NH₂

Concept Applied

NH₂ group in aniline donates electrons via resonance (+M), activating the ring for electrophilic attack....

Read Full Step-by-Step Solution →

Question #11

Practice Question

A.Azo dye
B.Phenylhydrazine
C.Diazotized aniline
D.Aniline hydrochloride

Concept Applied

Coupling reaction in acidic medium forms orange azo dye....

Read Full Step-by-Step Solution →

Question #12

Practice Question

A.Butan-1‑ol
B.Butan‑1‑amine
C.Butan‑2‑amine
D.Butan‑1‑yl bromide (unchanged)

Concept Applied

In Gabriel synthesis, the alkyl halide first reacts with potassium phthalimide to give N‑alkylphthalimide. Subsequent hydrolysis liberates the primary...

Read Full Step-by-Step Solution →

Question #13

Practice Question

A.A. A reaction that produces amines
B.B. A reaction that produces diazonium salts
C.C. A reaction that produces phenols
D.D. A reaction that produces aniline

Concept Applied

The Sandmeyer reaction is a type of electrophilic aromatic substitution reaction that produces phenols from diazonium salts....

Read Full Step-by-Step Solution →

Question #14

Practice Question

A.Aniline
B.N,N-Dimethylaniline
C.Methylaniline
D.Styrene

Concept Applied

Exhaustive methylation of aniline gives quaternary ammonium salt; Hoffmann elimination yields least substituted alkene — styrene....

Read Full Step-by-Step Solution →

Question #15

Practice Question

A.NaNO₂, HCl, 0–5 °C
B.NaNO₂, NaOH, 25 °C
C.KNO₃, H₂SO₄, 50 °C
D.NaNO₂, H₂SO₄, 0–5 °C

Concept Applied

Diazotisation requires nitrous acid (generated from NaNO₂ + HCl) at low temperature (0–5 °C) to keep the unstable diazonium ion from decomposing....

Read Full Step-by-Step Solution →

Question #16

Practice Question

A.Aniline > p-toluidine > ammonia
B.Ammonia > aniline > p-toluidine
C.p-Toluidine > aniline > ammonia
D.Ammonia > p-toluidine > aniline

Concept Applied

Electron-donating groups increase basicity; aniline is weakest due to resonance....

Read Full Step-by-Step Solution →

Question #17

Practice Question

A.Ethylamine
B.Methylamine
C.Propylamine
D.Dimethylamine

Concept Applied

In Hofmann bromamide reaction, R-CONH₂ → R-NH₂ with loss of CO₂. The alkyl group migrates, so carbon count decreases by one. Propanamide (C₂H₅CONH₂) g...

Read Full Step-by-Step Solution →

Question #18

Practice Question

Concept Applied

Diazotisation follows a 1:1 stoichiometry between aniline and NaNO₂. Hence, 0.10 mol of NaNO₂ is needed....

Read Full Step-by-Step Solution →

Question #19

Practice Question

A.Primary amine with one carbon less than the original amide
B.Alkyl bromide
C.Nitrile
D.Carboxylic acid

Concept Applied

The Hofmann bromamide reaction proceeds via bromination of the amide followed by base‑induced elimination, resulting in decarboxylation and formation ...

Read Full Step-by-Step Solution →

Question #20

Practice Question

A.Primary aliphatic amine
B.Secondary amine
C.Tertiary amine
D.Aromatic amine

Concept Applied

Gabriel synthesis produces only primary aliphatic amines via alkylation of phthalimide....

Read Full Step-by-Step Solution →

Question #21

Practice Question

A.+I effect of NH₂
B.Hyperconjugation
C.+M effect of NH₂
D.-I effect of NH₂

Concept Applied

NH₂ group in aniline donates electrons via resonance (+M), activating the ring for electrophilic attack....

Read Full Step-by-Step Solution →

Question #22

Practice Question

A.Azo dye
B.Phenylhydrazine
C.Diazotized aniline
D.Aniline hydrochloride

Concept Applied

Coupling reaction in acidic medium forms orange azo dye....

Read Full Step-by-Step Solution →

Question #23

Practice Question

A.Butan-1‑ol
B.Butan‑1‑amine
C.Butan‑2‑amine
D.Butan‑1‑yl bromide (unchanged)

Concept Applied

In Gabriel synthesis, the alkyl halide first reacts with potassium phthalimide to give N‑alkylphthalimide. Subsequent hydrolysis liberates the primary...

Read Full Step-by-Step Solution →

Question #24

Practice Question

A.A. A reaction that produces amines
B.B. A reaction that produces diazonium salts
C.C. A reaction that produces phenols
D.D. A reaction that produces aniline

Concept Applied

The Sandmeyer reaction is a type of electrophilic aromatic substitution reaction that produces phenols from diazonium salts....

Read Full Step-by-Step Solution →

Question #25

Practice Question

A.Aniline
B.N,N-Dimethylaniline
C.Methylaniline
D.Styrene

Concept Applied

Exhaustive methylation of aniline gives quaternary ammonium salt; Hoffmann elimination yields least substituted alkene — styrene....

Read Full Step-by-Step Solution →

Question #26

Practice Question

A.NaNO₂, HCl, 0–5 °C
B.NaNO₂, NaOH, 25 °C
C.KNO₃, H₂SO₄, 50 °C
D.NaNO₂, H₂SO₄, 0–5 °C

Concept Applied

Diazotisation requires nitrous acid (generated from NaNO₂ + HCl) at low temperature (0–5 °C) to keep the unstable diazonium ion from decomposing....

Read Full Step-by-Step Solution →

Question #27

Practice Question

A.Aniline > p-toluidine > ammonia
B.Ammonia > aniline > p-toluidine
C.p-Toluidine > aniline > ammonia
D.Ammonia > p-toluidine > aniline

Concept Applied

Electron-donating groups increase basicity; aniline is weakest due to resonance....

Read Full Step-by-Step Solution →

Question #28

Practice Question

A.Ethylamine
B.Methylamine
C.Propylamine
D.Dimethylamine

Concept Applied

In Hofmann bromamide reaction, R-CONH₂ → R-NH₂ with loss of CO₂. The alkyl group migrates, so carbon count decreases by one. Propanamide (C₂H₅CONH₂) g...

Read Full Step-by-Step Solution →

Question #29

Practice Question

Concept Applied

Diazotisation follows a 1:1 stoichiometry between aniline and NaNO₂. Hence, 0.10 mol of NaNO₂ is needed....

Read Full Step-by-Step Solution →

Question #30

Practice Question

A.Primary amine with one carbon less than the original amide
B.Alkyl bromide
C.Nitrile
D.Carboxylic acid

Concept Applied

The Hofmann bromamide reaction proceeds via bromination of the amide followed by base‑induced elimination, resulting in decarboxylation and formation ...

Read Full Step-by-Step Solution →

Question #31

Practice Question

A.Primary aliphatic amine
B.Secondary amine
C.Tertiary amine
D.Aromatic amine

Concept Applied

Gabriel synthesis produces only primary aliphatic amines via alkylation of phthalimide....

Read Full Step-by-Step Solution →

Question #32

Practice Question

A.+I effect of NH₂
B.Hyperconjugation
C.+M effect of NH₂
D.-I effect of NH₂

Concept Applied

NH₂ group in aniline donates electrons via resonance (+M), activating the ring for electrophilic attack....

Read Full Step-by-Step Solution →

Question #33

Practice Question

A.Azo dye
B.Phenylhydrazine
C.Diazotized aniline
D.Aniline hydrochloride

Concept Applied

Coupling reaction in acidic medium forms orange azo dye....

Read Full Step-by-Step Solution →

Question #34

Practice Question

A.Butan-1‑ol
B.Butan‑1‑amine
C.Butan‑2‑amine
D.Butan‑1‑yl bromide (unchanged)

Concept Applied

In Gabriel synthesis, the alkyl halide first reacts with potassium phthalimide to give N‑alkylphthalimide. Subsequent hydrolysis liberates the primary...

Read Full Step-by-Step Solution →

Question #35

Practice Question

A.A. A reaction that produces amines
B.B. A reaction that produces diazonium salts
C.C. A reaction that produces phenols
D.D. A reaction that produces aniline

Concept Applied

The Sandmeyer reaction is a type of electrophilic aromatic substitution reaction that produces phenols from diazonium salts....

Read Full Step-by-Step Solution →

Question #36

Practice Question

A.Aniline
B.N,N-Dimethylaniline
C.Methylaniline
D.Styrene

Concept Applied

Exhaustive methylation of aniline gives quaternary ammonium salt; Hoffmann elimination yields least substituted alkene — styrene....

Read Full Step-by-Step Solution →

Question #37

Practice Question

A.NaNO₂, HCl, 0–5 °C
B.NaNO₂, NaOH, 25 °C
C.KNO₃, H₂SO₄, 50 °C
D.NaNO₂, H₂SO₄, 0–5 °C

Concept Applied

Diazotisation requires nitrous acid (generated from NaNO₂ + HCl) at low temperature (0–5 °C) to keep the unstable diazonium ion from decomposing....

Read Full Step-by-Step Solution →

Question #38

Practice Question

A.Aniline > p-toluidine > ammonia
B.Ammonia > aniline > p-toluidine
C.p-Toluidine > aniline > ammonia
D.Ammonia > p-toluidine > aniline

Concept Applied

Electron-donating groups increase basicity; aniline is weakest due to resonance....

Read Full Step-by-Step Solution →

Question #39

Practice Question

A.Ethylamine
B.Methylamine
C.Propylamine
D.Dimethylamine

Concept Applied

In Hofmann bromamide reaction, R-CONH₂ → R-NH₂ with loss of CO₂. The alkyl group migrates, so carbon count decreases by one. Propanamide (C₂H₅CONH₂) g...

Read Full Step-by-Step Solution →

Question #40

Practice Question

Concept Applied

Diazotisation follows a 1:1 stoichiometry between aniline and NaNO₂. Hence, 0.10 mol of NaNO₂ is needed....

Read Full Step-by-Step Solution →

Question #41

Practice Question

A.Primary amine with one carbon less than the original amide
B.Alkyl bromide
C.Nitrile
D.Carboxylic acid

Concept Applied

The Hofmann bromamide reaction proceeds via bromination of the amide followed by base‑induced elimination, resulting in decarboxylation and formation ...

Read Full Step-by-Step Solution →

Question #42

Practice Question

A.Primary aliphatic amine
B.Secondary amine
C.Tertiary amine
D.Aromatic amine

Concept Applied

Gabriel synthesis produces only primary aliphatic amines via alkylation of phthalimide....

Read Full Step-by-Step Solution →

Question #43

Practice Question

A.+I effect of NH₂
B.Hyperconjugation
C.+M effect of NH₂
D.-I effect of NH₂

Concept Applied

NH₂ group in aniline donates electrons via resonance (+M), activating the ring for electrophilic attack....

Read Full Step-by-Step Solution →

Question #44

Practice Question

A.Azo dye
B.Phenylhydrazine
C.Diazotized aniline
D.Aniline hydrochloride

Concept Applied

Coupling reaction in acidic medium forms orange azo dye....

Read Full Step-by-Step Solution →

Question #45

Practice Question

A.Butan-1‑ol
B.Butan‑1‑amine
C.Butan‑2‑amine
D.Butan‑1‑yl bromide (unchanged)

Concept Applied

In Gabriel synthesis, the alkyl halide first reacts with potassium phthalimide to give N‑alkylphthalimide. Subsequent hydrolysis liberates the primary...

Read Full Step-by-Step Solution →

Question #46

Practice Question

A.A. A reaction that produces amines
B.B. A reaction that produces diazonium salts
C.C. A reaction that produces phenols
D.D. A reaction that produces aniline

Concept Applied

The Sandmeyer reaction is a type of electrophilic aromatic substitution reaction that produces phenols from diazonium salts....

Read Full Step-by-Step Solution →

Question #47

Practice Question

A.Aniline
B.N,N-Dimethylaniline
C.Methylaniline
D.Styrene

Concept Applied

Exhaustive methylation of aniline gives quaternary ammonium salt; Hoffmann elimination yields least substituted alkene — styrene....

Read Full Step-by-Step Solution →

Question #48

Practice Question

A.NaNO₂, HCl, 0–5 °C
B.NaNO₂, NaOH, 25 °C
C.KNO₃, H₂SO₄, 50 °C
D.NaNO₂, H₂SO₄, 0–5 °C

Concept Applied

Diazotisation requires nitrous acid (generated from NaNO₂ + HCl) at low temperature (0–5 °C) to keep the unstable diazonium ion from decomposing....

Read Full Step-by-Step Solution →

Question #49

Practice Question

A.Aniline > p-toluidine > ammonia
B.Ammonia > aniline > p-toluidine
C.p-Toluidine > aniline > ammonia
D.Ammonia > p-toluidine > aniline

Concept Applied

Electron-donating groups increase basicity; aniline is weakest due to resonance....

Read Full Step-by-Step Solution →

Question #50

Practice Question

A.Ethylamine
B.Methylamine
C.Propylamine
D.Dimethylamine

Concept Applied

In Hofmann bromamide reaction, R-CONH₂ → R-NH₂ with loss of CO₂. The alkyl group migrates, so carbon count decreases by one. Propanamide (C₂H₅CONH₂) g...

Read Full Step-by-Step Solution →
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