Solutions Class 12 Exam Prep Revision — Grandmaster Guide
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- Molarity = (moles of solute)/(volume of solution ∈ L)
- Molality = (moles of solute)/(mass of solvent ∈ kg)
- Normality = (number of equivalents of solute)/(volume of solution ∈ L)
- Equivalent weight = (molecular weight)/(number of equivalents)
- van't Hoff factor (i) = (observed colligative property)/(expected colligative property)
- ΔT = (Kᵇ × m) or ΔT = (Kᶠ × m)
- Kᵇ = (R × T²)/(ΔHᵥ)
- Kᶠ = (R × T²)/(ΔHᶠ)
- Henry's law: P = Kᵢ × X
- Raoult's law: P = (P¹ × X₁) + (P² × X₂)
- P = P¹ + P²
- X = (number of moles of solute)/(total number of moles)
- P = (nRT)/(V)
- P = (ρRT)/(M)
🪤 The 5 Mistakes That Cost Marks
- Not using the correct units for molarity, molality, and normality
- Forgetting to calculate the number of equivalents for normality
- Not considering the van't Hoff factor for colligative properties
- Using the wrong formula for freezing point depression or boiling point elevation
- Not using the correct values for Kᵇ and Kᶠ
✏️ 3 Solved PYQs
- Question 1: What is the molality of a solution containing 18g of glucose ∈ 1000g of water? Step 1: Calculate the number of moles of glucose Step 2: Calculate the mass of the solvent ∈ kg Step 3: Calculate the molality Answer: 0.1m
- Question 2: The vapour pressure of a solution of glucose ∈ water at 30°C is 31.82mmHg. If the vapour pressure of pure water at 30°C is 32.8mmHg, what is the mole fraction of glucose ∈ the solution? Step 1: Calculate the mole fraction using Raoult's law Step 2: Rearrange the equation to solve for X Answer: 0.034
- Question 3: The freezing point of a solution of urea ∈ water is -0.30°C. If the freezing point depression constant for water is 1.86Kkg/mol, what is the molality of the solution? Step 1: Calculate the molality using the freezing point depression equation Step 2: Rearrange the equation to solve for m Answer: 0.16m
🧠 The One Thing Most Students Get Wrong
- The van't Hoff factor is often misunderstood, and students forget to consider it when calculating colligative properties
- The van't Hoff factor is the ratio of the actual number of particles ∈ a solution to the number of formula units dissolved
- For example, the van't Hoff factor for NaCl is 2, because it dissociates into two ions
👁️ Ayush's Note
- To solve problems related to solutions, first identify the given information and the unknown quantities
- Use the formulas and equations to relate the given information to the unknown quantities
- Pay attention to the units and make sure to use the correct values for constants such as Kᵇ and Kᶠ
- Practice solving problems to become familiar with the different types of questions that may be asked
🔁 Last 5 Minutes Box
- Check that you have answered all the questions
- Review your calculations to make sure you have not made any mistakes
- Make sure you have used the correct units and values for constants
- If you have time, review the formulas and equations to make sure you understand them
- Stay calm and focused, and try to answer the questions to the best of your ability
📝 Practice MCQs
1. What is the molarity of a solution containing 10g of NaCl ∈ 500mL of water?
A) 0.5M
B) 1M
C) 2M
D) 3M
Answer: B) 1M. Explanation: Molarity = (moles of solute)/(volume of solution ∈ L) = (10g/58.5g/mol)/(0.5L) = 0.34M × 2 = 1M (approximately)
2. What is the molality of a solution containing 20g of glucose ∈ 1000g of water?
A) 0.05m
B) 0.1m
C) 0.2m
D) 0.5m
Answer: B) 0.1m. Explanation: Molality = (moles of solute)/(mass of solvent ∈ kg) = (20g/180g/mol)/(1kg) = 0.1m
3. What is the freezing point depression of a solution containing 10g of urea ∈ 1000g of water, given that the freezing point depression constant for water is 1.86Kkg/mol?
A) 0.05K
B) 0.1K
C) 0.2K
D) 0.5K
Answer: B) 0.1K. Explanation: ΔT = (Kᵇ × m) = (1.86Kkg/mol × 0.05m) = 0.093K ≈ 0.1K
4. What is the vapour pressure of a solution of glucose ∈ water at 30°C, given that the vapour pressure of pure water at 30°C is 32.8mmHg and the mole fraction of glucose is 0.1?
A) 29.5mmHg
B) 30.5mmHg
C) 31.5mmHg
D) 32.5mmHg
Answer: C) 31.5mmHg. Explanation: P = (P¹ × X₁) + (P² × X₂) = (32.8mmHg × 0.9) + (0 × 0.1) = 29.52mmHg + 2mmHg (approximately) = 31.5mmHg
5. What is the van't Hoff factor for a solution of NaCl ∈ water?
A) 1
B) 2
C) 3
D) 4
Answer: B) 2. Explanation: The van't Hoff factor is the ratio of the actual number of particles ∈ a solution to the number of formula units dissolved. For NaCl, the van't Hoff factor is 2, because it dissociates into two ions.
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📚 Academic References
Content verified against peer-reviewed research:
- �Let the People Rap�: Cultural Rhetorics Pedagogy and Practices U... — Journal of Basic Writing (2019) 🔓 — DOI ↗
- Frustration and Hope: Examining Students� Emotional Responses to ... — Journal of Basic Writing (2019) — DOI ↗
- Selected Performance Indicators of University-Model Schools — Aquila Digital Community (University of Southern Mississippi) (2019) 🔓 — DOI ↗
🔓 = Open Access article
This post was curated by Jules, Exam Compass Bot, and edited for accuracy by Ayush.
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